Unit · year 3
CU-307 · Electrochemistry & Interfaces
Threads energy · equilibrium24 lectures4 results
The physical chemistry of electrolytes and the electrode interface.
PREREQUISITES
Lectures
| L01 | Electrolyte Solutions: Ions in Water — |
| L02 | Ion–Solvent Interactions and Solvation — |
| L03 | Conductivity of Electrolytes |
| L04 | Molar Conductivity and Dilution |
| L05 | Kohlrausch's Law |
| L06 | Independent Migration of Ions |
| L07 | Transport Numbers and Ionic Mobility |
| L08 | Activity and Activity Coefficients — |
| L09 | Ionic Strength |
| L10 | The Debye–Hückel Model |
| L11 | The Debye–Hückel Limiting Law |
| L12 | The Extended Law and Its Range of Validity |
| L13 | The Electrode–Solution Interface |
| L14 | The Helmholtz Model |
| L15 | Gouy–Chapman and Stern Models |
| L16 | Zeta Potential and Colloid Stability |
| L17 | Electrode Kinetics: Beyond Equilibrium |
| L18 | Overpotential and Current Density |
| L19 | The Butler–Volmer Equation |
| L20 | The Tafel Plot |
| L21 | Mass Transport and Limiting Current |
| L22 | Voltammetry and Electroanalysis — |
| L23 | Corrosion Kinetics |
| L24 | Synthesis: The Interface as the Reaction Site |
Results in this unit
T-102
The Debye-Huckel theory
Activity coefficients in dilute electrolyte solutions.
T-103
The electrical double layer
Structure of the electrode-solution interface.
T-104
The Butler-Volmer equation
Electrode current as a function of overpotential.
T-105
Conductivity of electrolytes
Kohlrausch's law of independent ionic migration.